I have not....I do have some 100% organic powdered spirulina that is as fine or finer then the supplements we give. I will start trying a every other or every third feeding with some dusted flies and see if I can see any results. I am sure it will take a couple weeks of supplementing before there is any results if there is any.....
I welcome the results of your "experiment". I'd love to find something that works with blues and greens. Not only for frogs but for fish too.
I don't think there is any supplement that would enhance blue or green - or if there is it's a well kept secret! The only thing I could suggest is change your lighting to focus on the blues and greens - I'm sure reef keepers could suggest some light temps etc.